[1]张昱,徐琴琴,银建中.超临界流体技术在石墨烯制备中的应用[J].应用科技,2015,(05):72-77.[doi:10.11991/yykj.201501010]
 ZHANG Yu,XU Qinqin,YIN Jianzhong.Application of supercritical fluid technology in the preparation of graphene[J].yykj,2015,(05):72-77.[doi:10.11991/yykj.201501010]
点击复制

超临界流体技术在石墨烯制备中的应用(/HTML)
分享到:

《应用科技》[ISSN:1009-671X/CN:23-1191/U]

卷:
期数:
2015年05期
页码:
72-77
栏目:
材料与化学
出版日期:
2015-10-05

文章信息/Info

Title:
Application of supercritical fluid technology in the preparation of graphene
作者:
张昱12 徐琴琴2 银建中2
1. 内蒙古工业大学 化工学院, 内蒙古 呼和浩特 010051;
2. 大连理工大学 化工机械学院, 辽宁 大连 116024
Author(s):
ZHANG Yu12 XU Qinqin2 YIN Jianzhong2
1. School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China;
2. School of Chemical Machinery, Dalian University of Technology, Dalian 116024, China
关键词:
超临界流体超临界二氧化碳石墨烯剥离绿色化学
Keywords:
supercritical fluids(SCF)supercritical carbon dioxidegrapheneexfoliationgreen chemistry
分类号:
O613;TB332
DOI:
10.11991/yykj.201501010
文献标志码:
A
摘要:
石墨烯因其独特的二维晶体结构和优良的力学、电学、热学和光学特性,成为近几年材料领域的研究热点.要实现石墨烯产业化,其关键问题是探索大规模、高质量、低成本的石墨烯制备技术.超临界流体具有似气似液的优越性质,将其用于直接剥离制备石墨烯,具有高效、环保、产物质量高等优势.本文综述了近年来超临界流体技术应用于直接液相或气相剥离法制备石墨烯的研究进展,着重讨论了超临界二氧化碳辅助超声处理制备石墨烯的优势,以及超临界流体直接剥离法制备石墨烯的机理,在此基础上,指出目前文献中尚存在的不足以及亟待解决的关键问题.
Abstract:
Graphene has become a hot topic in recent years for its unique two-dimensional crystal structure and excellent mechanical, electrical, thermal, and optical properties. In order to realize graphene industrialization, it is a key problem to explore a large-scale preparing method of graphene with high quality and low cost. Supercritical fluids have advantages of liquid-like high densities and gas-like low viscosities. It is an environmentally benign and highly efficient method to prepare high quality graphene by using the supercritical fluids exfoliation method. This article introduces the research progress in recent years of preparing graphene using the direct liquid phase method or gas phase exfoliation method, emphasizing on the advantage of supercritical carbon dioxide assisted ultrasonic treatment and the mechanism of supercritical fluids exfoliation method. In addition, the inadequacies in the literatures and the research direction in the future are also discussed.

参考文献/References:

[1] NOVOSELOV K S, GEIM A K, MOROSOV S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004, 306(5696): 666-669.
[2] NETO A H C, GUINEA F, PERES N M R, et al. The electronic properties of graphene[J]. Reviews of Modern Physics, 2009,81(1): 109-162.
[3] BETS K V, YAKOBSON B I. Spontaneous twist and intrinsic in stabilities of pristine graphene nanoribbons[J]. Nano Research, 2009,2(2): 161-166.
[4] RODRIGO V S, SERGIO H D, MARCELA M O, et al. Tri-layer graphene films produced by mechanochemical exfoliation of graphite[J]. Carbon, 2013, 57: 410-415.
[5] BALANDIN A A, GHOSH S, BAO W, et al. Superior thermal conductivity of single-layer graphene[J]. Nano Letters, 2008, 8(3): 902-907.
[6] GEIM A K, NOVOSELOV K S. The rise of graphene[J]. Nature Materials, 2007, 6(3): 183-191.
[7] 傅强, 包信和. 石墨烯的化学研究进展[J]. 科学通报, 2009, 54(18): 2657-2666.
[8] 袁小亚. 石墨烯的制备研究进展[J]. 无机材料学报, 2011, 26(6): 561-570.
[9] 任文才, 高力波, 马来鹏, 等. 石墨烯的化学气相沉积法制备[J]. 新型炭材料, 2011, 26(1): 71-80.
[10] HERNANDEZ Y, NICOLOSI V, LOTYA M, et al. High-yield production of graphene by liquid-phase exfoliation of graphite[J]. Nature Nanotechnology, 2008, 3(9): 563-568.
[11] GUARDIA L, FERNANDEZ-Merino M J, PAREDES J I, et al. High-throughput production of pristine graphene in an aqueous dispersion assisted by non-ionic surfactants[J]. Carbon, 2011, 49(5) : 1653-1662.
[12] DU W,LU J,SUN P,et al. Organic salt-assisted liquid-phase exfoliation of graphite to produce high- quality graphene[J]. Chemical Physics Letters, 2013, 568: 198-201.
[13] LOTYA M,HERNANDEZ Y,KING P J,et al. Liquid phase production of graphene by exfoliation of graphite in surfactant /water solutions[J]. Journal of the American Chemical Society, 2009, 131(10) : 3611-3620.
[14] ZHANG M, PARAJULI R R,MASRTOGIOVANNI D,et al. Production of graphene sheets by direct dispersion with aromatic healing agents[J]. Small, 2010, 6(10): 1100-1107.
[15] 石梦燕, 张晓凤, 王孝英, 等. 直接液相剥离法制备无缺陷石墨烯[J]. 南京师范大学学报, 2014, 14(2) :1-7.
[16] 王雅琼,倪敏,王仲辉, 等. 超临界CO2中SBA-15对无机盐吸附的动力学[J].应用科技,2011, 38(12):50-54.
[17] 徐琴琴. 超临界流体沉积法制备纳米复合材料[D]. 大连: 大连理工大学化工学院, 2007: 38-46.
[18] 银建中, 马晓荣, 张宪阵, 等. CO2膨胀液体热力学特性及在化学反应中的应用[J].化学进展, 2008, 20: 1251- 1262.
[19] 商紫阳, 银建中, 马震, 等.超临界甲醇法制备生物柴油过程的热力学行为[J].应用科技, 2011, 38(1): 5-9.
[20] 李琪, 银建中. 超临界二氧化碳和离子液体微乳液体系的热力学性质及应用[J]. 应用科技, 2015, 42(1): 70-74.
[21] SERHATKULU G K, DILEK C, GULARI E. Supercritical CO2 intercalation of layered silicates[J]. Journal of Super- critical Fluids, 2006,39(2): 264-270.
[22] PU Nenwen, WANG Chungan, SUNG Yu, et al. Production of few-layer graphene by supercritical CO2 exfoliation of graphite[J]. Material Letter, 2009, 63(23): 1987-1989.
[23] RANGAPPA D, SONE K, WANG M S, et al. Rapid and Direct Conversion of Graphite Crystals into High-Yielding, Quality Good-Graphene by Supercritical Fluid Exfo- liation[J]. Chemistry-A European Journal, 2010, 16 (22): 6488-6494.
[24] GAO Y H, SHI W, WANG W C, et al. Ultrasonic-Assisted Production of Graphene with High Yield in Supercritical CO2 and Its High Electrical Conductivity Film[J].Industrial & Engineering Chemistry Research, 2014,53(7): 2839- 2845.
[25] WANG Y, ZHOU C H, WANG W C, et al. Preparation of Two Dimensional Atomic Crystals BN, WS2, and MoS2 by Supercritical CO2 Assisted with Ultrasound[J]. Industrial & Engineering Chemistry Research, 2013, 52(11): 4379- 4382.
[26] 胡玉婷. 在超临界二氧化碳体系中石墨烯剥离技术的研究[D]. 济南: 山东大学理学院, 2014: 28-35.
[27] 郑晓莉. 超临界CO2辅助制备碳纳米管及石墨烯基纳米杂化材料的研究[D]. 郑州: 郑州大学, 2012: 16-23.
[28] ZHENG X, XU Q, LI J et al. High-throughput, direct exfoliation of graphite to graphene via a cooperation of supercritical CO2 and pyrene-polymers[J]. RSC Advances, 2012, 2(28): 10632-10638.
[29] 李利花. 超临界二氧化碳辅助石墨烯的制备、功能化及在燃料电池中的应用[D]. 郑州: 郑州大学, 2013: 35-41.
[30] LI L H, ZHENG X X, WANG J J, et al. Solvent-exfoliated and functionalized graghene with assistance of supercritical carbon dioxide[J]. ACS Sustainable Chemistry & Engineering, 2013, 1(1): 144-151.
[31] LI L H, ZHANG J N, LIU YQ, et al. Facile fabrication of Pt nanoparticles on 1-pyrenamine functionalized graphene nanosheets for methenol electrooxidation[J]. ACS Sustainable Chemistry & Engineering, 2013, 1(5): 527-533.
[32] 袁利利. 超临界CO2在溶液法制备石墨烯中的作用的第一性原理研究[D]. 郑州: 郑州大学, 2014: 12-18.
[33] WU B, Yang X N. A molecular simulation of interactions between graphene nanosheets and supercritical CO2[J]. Colloid Interface Science, 2011, 361:1-8.
[34] 吴娟霞, 徐华, 张锦. 拉曼光谱在石墨烯结构表征中的应用[J]. 化学学报, 2014, 72(3): 301-318.
[35] 韩布兴. 超临界流体科学与技术[M]. 北京: 中国石化出版社, 2005: 3-4.
[36] BYUN H S, KIM N H, KWAK C. Measurements and modeling of high-pressure phase behavior of binary CO2-amides systems[J]. Fluid phase equilibra, 2003, 208(1): 53-68.
[37] MOORE V C, STRANO M S, HAROZ E H, et al. Indi-vidually suspended single-walled carbon nanotubes in various surfactants[J]. Nano letters, 2003, 3(10): 1379- 1382.
[38] HAO R, QIAN W, ZHANG L, et al. Aqueous dispersions of TCNQ-anion-stabilized graphene sheets[J]. Chemical communications, 2008, (48): 6576-6578.

相似文献/References:

[1]银建中,王伟彬,胡大鹏,等.用修正的简化局部密度理论模拟超临界流体系统的吸附特性[J].应用科技,2010,(08):58.[doi:10.3969/j.issn.1009-671X.2010.08.014]
 YIN Jian-zhong,WANG Wei-bin,HU Da-peng,et al.Adsorption properties simulation for supercritical fluid systems using revised simplified local density theory[J].yykj,2010,(05):58.[doi:10.3969/j.issn.1009-671X.2010.08.014]
[2]郝刘丹,刘一凡,赵孟姣,等.木质纤维素的超临界二氧化碳预处理技术[J].应用科技,2014,(05):67.[doi:10.3969 / j.issn.1009⁃671X.201311004]
 ,,et al.Supercritical carbon dioxide pretreatment technology of lignocellulose[J].yykj,2014,(05):67.[doi:10.3969 / j.issn.1009⁃671X.201311004]
[3]李琪,银建中.超临界甲醇法连续制备生物柴油工艺研究[J].应用科技,2016,(02):75.[doi:10.11991/yykj.201504012]
 LI Qi,YIN Jianzhong.A process for continuously preparing biodiesel by supercritical methanol[J].yykj,2016,(05):75.[doi:10.11991/yykj.201504012]

备注/Memo

备注/Memo:
收稿日期:2015-1-17;改回日期:。
基金项目:国家自然科学基金资助项目(21376045).
作者简介:张昱(1973-),女,副教授;银建中(1964-),男,教授,博士生导师.
通讯作者:银建中,E-mail:jzyin@dlut.edu.cn.
更新日期/Last Update: 2015-10-20